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The molecule makes three changes to the native hormone fragment: a lactam bridge between the aspartate side-chain carboxyl at position 5 and the lysine side-chain amine at position 10, inversion to D-phenylalanine at position 7, and substitution of norleucine for the oxidation-prone methionine at position 4

doi: 10.1038/s41564-017-0089-z, 89 Shen-GuntherJ.XiaQ.CaiH.WangY